Toxic Material in Firecrackers

In News

Recently, the Supreme Court (SC) lamented the rampant violation of its ban on use of toxic ingredients in the firecracker industry.

About

  • The Supreme Court highlighted the findings of preliminary enquiry by the CBI into the firecracker industry, including in Tamil Nadu.
  • A chemical analysis of the samples of finished and semi-finished firecrackers and raw materials taken from the manufacturers showed Barium content.
  • The court stated that loose quantities of Barium were purchased from the market. 
  • Firecracker covers did not show the manufacture or expiry dates.
  • The Supreme Court told the firecracker manufacturers that the right to life of innocent citizens was more precious than the right to employment of workers.

Image Courtesy: TH

Chemistry of fireworks

  • Explosive fireworks depend on four primary ingredients — 
    • oxidiser, 
    • fuel, 
    • colouring agents & 
    • Binder.

Image Courtesy: ET 

  • The oxidisers in fireworks are chemicals that release oxygen to allow the explosion to take place. Ex: Nitrates, chlorates.
  • The fuel for burning is usually charcoal.
  • Colouring agents impart desired colours like aluminium compounds for brilliant whites, barium nitrate for greens.
  • Binders are used to hold the mixture of the firework together in a paste while burning.
  • Also, other metals like titanium & strontium are added to regulate the speed of the burning reaction.

Image Courtesy: ET 

 

Existing Guidelines

  • Currently, guidelines exist for four types of explosive firecrackers — atom bombs, Chinese crackers, garland crackers and maroons.
  • The guidelines for these were drawn by PESO in 2008 after the Supreme Court ordered it to regulate their composition.
  • According to these guidelines, the sulphur, nitrate & aluminium power contents must not exceed 20%, 57%, & 24% respectively.
  • In July 2016 the SC ordered that no firecrackers shall contain antimony, lithium, mercury, arsenic and lead.

Image Courtesy: ET 

Benefits of Banning Toxic Firecrackers

  • Eco-Friendly Diwali-  Lesser Air Pollution
  • Lesser Noise Pollution
  • Lesser diseases
  • Lesser Clutter Post-Diwali
  • Lesser Accidents
  • Avoiding Inhuman Conditions of Workers
  • Fewer Disturbances to Animals and Birds
  • Fewer Chinese Products
  • Money Savings

Challenges

  • Sale and manufacture regulation
  • Behavioral change amongst people
  • Regulating time for bursting
  • Making switch by industry towards improved or green crackers

 

Way Forward

  • There should be a balance between employment, unemployment and the right to life and health of citizens. 
  • Lives of many can not be sacrificed for a few. 
  • The  prime focus should be the right to life of innocent people.

What are Green Crackers?

  • The SC identifies usable crackers in two categories: 
    • Improved crackers:
      • Improved crackers are those which avoid the use of ash as filler material (to reduce PM emission by 15-20 per cent) and usage of charcoal within the limitation that Petroleum and Explosives Safety Organisation (PESO) prescribes.  
    • Green crackers: 
      • Green crackers are safe water and air sprinklers that emit less sound and light. 
      • They also ensure a PM reduction of 30-35 per cent and reduction in NOx and SO2 due to in-situ water generation acting as dust suppressant. 
      • These also cost less owing to usage of low cost oxidants. 
    • The judgment (of promoting Green Cracker) may prove to be a great initiative towards setting new standards for manufacture of firecrackers and spreading awareness about firecracker emissions. 
    • Implementing this would remain a challenge, seeing how authorities are still struggling with noise standards for crackers despite laws being formulated for the same in 1999. This may also make industries switch to cleaner crackers.

Source: TH